ASTM F75 Alloys: A Systematic Review of Microstructural Characteristics and Manufacturing Advances from Conventional to Laser-Based Techniques with Bibliometric Analysis

Authors

  • Raghad Ahmed Al-Aloosi University of Baghdad Author
  • Wisam T. Abbood University of Baghdad Author
  • Enas A. Khalid University of Baghdad Author
  • Wassan S. Abd Al-Sahb University of Baghdad Author
  • Nazar Kais AL-Karkhi University of Baghdad Author
  • Oday I. Abdullah University of Baghdad, Baghdad, Iraq. Al-Naji University, Baghdad, Iraq. Al-Farabi Kazakh National University, Almaty, Kazakhstan. Author
  • Somer Nacy San Diego State University Author
  • Adawiya J. Haider University of Technology Author
  • M. N. Mohammed Gulf University Author

Keywords:

Additive manufacturing, ASTM F75 alloys, Laser powder bed fusion, Microstructural characterization, Mechanical properties

Abstract

This study provides a systematic and bibliometric review of
ASTM F75 cobalt–chromium alloys, focusing on
microstructure and the shift from conventional to laserbased manufacturing. Using combined analytical methods, it
evaluates microstructure, mechanical properties, corrosion
behavior, and biocompatibility. Results show that laserbased techniques such as LPBF and DMLS produce finer grain
sizes (1–10 µm vs. 50–200 µm), leading to improved hardness
(20–40%) and tensile strength (15–30%). Despite challenges
like residual stress and process optimization, these methods
show strong potential for high-performance and sustainable
applications.

References

Muñoz, I. A., and Mischler, S. (2011). Effect of the environment on wear ranking and

corrosion of biomedical CoCrMo alloys. Journal of Materials Science: Materials in

Medicine, 22(3), 437-450.

Hedberg, Y., and Wallinder, O. I. (2014). Metal release and speciation of released

chromium from a biomedical CoCrMo alloy into simulated physiologically relevant

solutions. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 102(4),

-699.

Mantrala, K. M., Das, M., Balla, V. K., Rao, C. S., and Rao, V. K. (2014). Laser-deposited

CoCrMo alloy: Microstructure, wear, and electrochemical properties. Journal of Materials

Research, 29(17), 2021-2027.

Guoqing, Z., Yongqiang, Y., Hui, L., Changhui, S., and Zimian, Z. (2017). Study on the

quality and performance of CoCrMo alloy parts manufactured by selective laser melting.

Journal of Materials Engineering and Performance, 26(6), 2869-2877.

Bawane, K. K., Srinivasan, D., and Banerjee, D. (2018). Microstructural evolution and

mechanical properties of direct metal laser-sintered (DMLS) CoCrMo after heat

treatment. Metallurgical and Materials Transactions A, 49(9), 3793-3811.

Song, C., Zhang, M., Yang, Y., Wang, D., and Jia-Kuo, Y. (2018). Morphology and properties

of CoCrMo parts fabricated by selective laser melting. Materials Science and Engineering:

A, 713, 206-213.

Guoqing, Z., Junxin, L., Jin, L., Chengguang, Z., and Zefeng, X. (2018). Simulation analysis

and performance study of CoCrMo porous structure manufactured by selective laser

melting. Journal of Materials Engineering and Performance, 27(5), 2271-2280.

Bandyopadhyay, A., Shivaram, A., Isik, M., Avila, J. D., Dernell, W. S., and Bose, S. (2019).

Additively manufactured calcium phosphate reinforced CoCrMo alloy: Bio-tribological

and biocompatibility evaluation for load-bearing implants. Additive manufacturing, 28,

-324.

Li, J., Ren, H., Liu, C., and Shang, S. (2019). The effect of specific energy density on

microstructure and corrosion resistance of CoCrMo alloy fabricated by laser metal

deposition. Materials, 12(8), 1321.

Tonelli, L., Fortunato, A., and Ceschini, L. (2020). CoCr alloy processed by selective laser

melting (SLM): Effect of laser energy density on microstructure, surface morphology, and

hardness. Journal of Manufacturing Processes, 52, 106-119.

Santos, C. D., Habibe, A. F., Simba, B. G., Lins, J. F. C., Freitas, B. X. D., and Nunes, C. A.

(2020). CoCrMo-base alloys for dental applications obtained by selective laser melting

(SLM) and CAD/CAM milling. Materials Research, 23(2), e20190599.

Zhao, F., Guo, T., Li, Q., Yin, Y., Zhang, R., and Nan, X. (2022). Effect of solution aging

treatment on microstructure and properties of Fe-0.5 C-11Cr corrosion resistant alloy by

laser cladding. Journal of Alloys and Compounds, 922, 166142.

Li, H., Wang, M., Lou, D., Xia, W., and Fang, X. (2020). Microstructural features of

biomedical cobalt–chromium–molybdenum (CoCrMo) alloy from powder bed fusion to

aging heat treatment. Journal of Materials Science & Technology, 45, 146-156.

Miyake, M., Matsuda, T., Sano, T., Hirose, A., Shiomi, Y., and Sasaki, M. (2020).

Microstructure and mechanical properties of additively manufactured CoCrW alloy using

laser metal deposition. Welding in the World, 64(8), 1397-1407.

Viderščak, D., Schauperl, Z., Šolić, S., Ćatić, A., Godec, M., Kocijan, A., Paulin, I., and Donik,

Č. (2021). Additively manufactured commercial Co-Cr dental alloys: Comparison of

microstructure and mechanical properties. Materials, 14(23), 7350.

Kosec, T., Leban, M. B., Kurnik, M., and Kopač, I. (2021). Comparison of the corrosion

properties of cocrmo dental alloys in artificial saliva. Materials and Technology, 55(6),

-824.

Wai Cho, H. H., Takaichi, A., Kajima, Y., Htat, H. L., Kittikundecha, N., Hanawa, T., and

Wakabayashi, N. (2021). Effect of post-heat treatment cooling conditions on

microstructures and fatigue properties of cobalt chromium molybdenum alloy fabricated

through selective laser melting. Metals, 11(7), 1005.

Hu, Y., Dong, C., Kong, D., Ding, J., He, X., Ni, X., Zhang, L., and Li, X. (2021). Effects of postproduction heat treatment on the mechanical and corrosion behaviour of CoCrMoW alloy manufactured through selective laser melting. Materials Today Communications,

, 102994.

Saini, J. S., Dowling, L., Trimble, D., and Singh, D. (2021). Mechanical properties of

selective laser melted CoCr alloys: A review. Journal of Materials Engineering and

Performance, 30(12), 8700-8714.

Sahasrabudhe, H., Traxel, K. D., and Bandyopadhyay, A. (2021). Understanding wear

behavior of 3D-printed calcium phosphate-reinforced CoCrMo in biologically relevant

media. Journal of the mechanical behavior of biomedical materials, 120, 104564.

Mace, A., Khullar, P., Bouknight, C., and Gilbert, J. L. (2022). Corrosion properties of low

carbon CoCrMo and additively manufactured CoCr alloys for dental applications. Dental

Materials, 38(7), 1184-1193.

Dong, X., Li, N., Yu, J., Qu, Y., Wu, M., Zhou, Y., Shi, H., Peng, H., Zhang, Y., and Yan, J.

(2022). Effect of grain boundary character on isothermal phase transformation and

mechanical properties of Co-Cr-Mo alloy fabricated by selective laser melting. Journal of

Alloys and Compounds, 903, 163904.

Reimann, L., Brytan, Z., and Jania, G. (2022). Influence of filler metal on electrochemical

characteristics of a laser-welded Co-Cr-MoW alloy used in prosthodontics. Materials,

(16), 5721.

Hu, Y., Yao, J., Ao, M., and Dong, C. (2022). Nanoscale precipitate in PBF-LB-manufactured

CoCrMoW alloy and its effect on passive behaviour. Materials Letters, 319, 132295.

Liu, Y., Mace, A., Lee, H., Camargo, M., and Gilbert, J. L. (2022). Single asperity sub-nano

to nanoscale wear and tribocorrosion of wrought CoCrMo and additively manufactured

CoCrMoW alloys. Tribology International, 174, 107770.

Saini, J. S., Dowling, L., Trimble, D., and Singh, D. (2021). Mechanical properties of

selective laser melted CoCr alloys: A review. Journal of Materials Engineering and

Performance, 30(12), 8700-8714.

Qin, P., Chen, L. Y., Liu, Y. J., Zhao, C. H., Lu, Y. J., Sun, H., and Zhang, L. C. (2023). Corrosion

behavior and mechanism of laser powder bed fusion produced CoCrW in an acidic NaCl

solution. Corrosion Science, 213, 110999.

Jiang, W., An, X., Xiao, C., Ni, S., and Song, M. (2023). Effects of heat treatment on the

microstructure and properties of a face-centered cubic CoCrMoW alloy prepared via laser

powder bed fusion. Journal of Alloys and Compounds, 963, 171212.

Shang, R., Yang, B., and Li, Y. (2023). Enhanced anti-corrosion performance of co-cr-mo

alloy in molten Al by prior oxidation treatment. Materials, 16(23), 7449.

Zhang, Y., Lin, W., Zhai, Z., Wu, Y., Yang, R., and Zhang, Z. (2023). Enhancing the

mechanical property of laser powder bed fusion CoCrMo alloy by tailoring the

microstructure and phase constituent. Materials Science and Engineering: A, 862,

Atapour, M., Sanaei, S., Wei, Z., Sheikholeslam, M., Henderson, J. D., Eduok, U., Hosein,

Y. K., Holdsworth, D.W., Hedberg, Y. S., and Ghorbani, H. R. (2023). In vitro corrosion and

biocompatibility behavior of CoCrMo alloy manufactured by laser powder bed fusion

parallel and perpendicular to the build direction. Electrochimica Acta, 445, 142059.

Al-Aloosi, R. A., Comakli, O., Yazici, M., and Taha, Z. A. (2023). Influence of scanning

velocity on a CoCrMoW alloy built via selective laser melting: Microstructure, mechanical,

and tribological properties. Journal of Materials Engineering and Performance, 32(15),

-6724.

Preda, L., Leau, S. A., Donath, C., Neacsu, E. I., Maxim, M. E., Sătulu, V., Paraschiv, A., and

Marcu, M. (2023). Investigation of long-term corrosion of CoCrMoW alloys under

simulated physiological conditions. Metals, 13(11), 1881.

Mace, A., and Gilbert, J. L. (2023). Low cycle fretting and fretting corrosion properties of

low carbon CoCrMo and additively manufactured CoCrMoW alloys for dental and

orthopedic applications. Journal of Biomedical Materials Research Part B: Applied

Biomaterials, 111(9), 1600-1613.

Mohamed, L. Z., Elsayed, A. H., Elkady, O. A., and Abolkassem, S. A. (2023). Physicomechanical, microstructure, and chemical properties of Si/Ti/Nb additions to CoCrMoW

medium entropy alloys. Journal of Materials Research and Technology, 24, 9897-9914.

Man, K., Mazumder, S., Dahotre, N. B., and Yang, Y. (2023). Surface nanostructures

enhanced biocompatibility and osteoinductivity of laser-additively manufactured

CoCrMo alloys. ACS Omega, 8(50), 47658-47666.

Klimek, L., Bułhak, B., and Śmielak, B. (2024). A comparison of the structure and selected

mechanical properties of Cr/Co alloys obtained by casting and selective laser melting.

Journal of Functional Biomaterials, 15(3), 61.

Mani, G., Porter, D., Collins, S., Schatz, T., Ornberg, A., and Shulfer, R. (2024). A review

on manufacturing processes of cobalt-chromium alloy implants and its impact on

corrosion resistance and biocompatibility. Journal of Biomedical Materials Research Part

B: Applied Biomaterials, 112(6), e35431.

Pellegrini, A., Lavecchia, F., Guerra, M. G., and Galantucci, L. M. (2024). Analysis of

microstructure and mechanical properties of CoCrMo alloys processed by metal binder

jetting multi-step technique. Journal of Manufacturing and Materials Processing, 8(6),

Chen, J., Ding, X., Wang, J., Xie, Z., and Wang, S. (2024). Corrosion behavior, metal ions

release and wear resistance of TiN coating deposited on SLM CoCrMo alloy by magnetron

sputtering. Journal of Alloys and Compounds, 1002, 175319.

Alaloosi, R. A., Çomakli, O., Yazici, M., and Taha, Z. A. (2024). Effect of scan speed on

corrosion and tribocorrosion properties of cobalt-chromium alloy in situ produced by

selective laser melting. Rapid Prototyping Journal, 30(3), 405-414.

Sing, S. L., Huang, S., and Yeong, W. Y. (2020). Effect of solution heat treatment on

microstructure and mechanical properties of laser powder bed fusion produced cobalt28chromium-6molybdenum. Materials Science and Engineering: A, 769, 138511.

Vidyasagar, K. C., and Kalyanasundaram, D. (2024). Enhanced corrosion resistance of

CoCrMo by laser-based surface modification. Surface Engineering, 40(1), 100-111.

Varol, T., Aksa, H. C., Yıldız, F., Akçay, S. B., Kaya, G., and Beder, M. (2024). Influence of

post processing on the mechanical properties and wear behavior of selective laser melted

Co-Cr-Mo-W alloys. Tribology International, 192, 109336.

Al-Aloosi, R. A., Taha, Z. A. T., and Çomakli, O. Ç. O. (2024). Influence of scanning velocity

on Co24. 7Cr5Mo5. 4W alloy built via selective laser melting on roughness properties.

Iraqi Journal of Laser, 23(1), 24-37.

Li, H., Song, B., Wang, Y., Zhang, J., Zhao, W., and Fang, X. (2024). Laser powder bed

fusion process optimization of CoCrMo alloy assisted by machine-learning. Journal of

Materials Research and Technology, 33, 3901-3910.

De La Cruz, L. G., Alvaredo, P., Torralba, J. M., and Campos, M. (2024). Material extrusion:

A promising tool for processing CoCrMo alloy with excellent wear resistance for

biomedical applications. Materials & Design, 244, 113089.

Ma, L. Y., Sun, F. Y., Li, Y., and Yu, H. (2024). Mechanical property, corrosion behavior

and cytocompatibility of CoCrMo for dental application: A comparative study of cast and

laser powder bed fusion. Journal of the Mechanical Behavior of Biomedical Materials,

, 106788.

Al Jabbari, Y. S., Dimitriadis, K., Sufyan, A., and Zinelis, S. (2024). Microstructural and

mechanical characterization of six Co-Cr alloys made by conventional casting and

selective laser melting. The Journal of Prosthetic Dentistry, 132(3), 646-e1.

Jiang, W., Li, R., He, J., Ni, S., Wang, L., Chen, Z., Huang, Y., Li, C., Yi, J., and Song, M.

(2024). Nitrogen-doping assisted local chemical heterogeneity and mechanical properties

in CoCrMoW alloys manufactured via laser powder bed fusion. Advanced Powder

Materials, 3(5), 10027.

Mazumder, S., Boban, J., and Ahmed, A. (2025). A comprehensive review of recent

advancements in 3D-printed Co-Cr-based alloys and their applications. Journal of

Manufacturing and Materials Processing, 9(5), 169.

Aktürk, D., Yildiz, M. T., Yurtkuran, E., and Babacan, N. (2025). Microstructural and fatigue

properties of dental structures produced via selective laser melting: Comparing Co-CrMo, Co-Cr-Mo-W and Co-Cr-W alloys. Rapid Prototyping Journal, 31(6), 1280-1290.

Dai, L., Song, C., Fu, H., Chen, H., Yan, Z., Liu, Z., Li, R., Wang, A., Yang, Y., and Yu, J. K.

(2025). Recrystallization induced by heat treatment regulates the anisotropic behavior of

CoCrMo alloys fabricated by laser powder bed fusion. Materials Futures, 4(2), 025001.

Nothnagel, R. M., Vukonic, L., Bauer, C., Váradi, T., Linhardt, P., Franek, F., Nehrer, S., and

Ripoll, R. M. (2025). Tribocorrosion performance and cytotoxicity of additive

manufactured CoCrMo: A benchmark against wrought CoCrMo. Journal of Bio-and TriboCorrosion, 11(1), 2.

Avanzini, A., Petrogalli, C., and Cornacchia, G. (2025). Tribological behavior of a selective

laser melted CoCrMo alloy under different heat treatment, loading, and sliding

conditions. Tribology Transactions, 68(3), 613-19.

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Published

2027-03-01