ASTM F75 Alloys: A Systematic Review of Microstructural Characteristics and Manufacturing Advances from Conventional to Laser-Based Techniques with Bibliometric Analysis
Keywords:
Additive manufacturing, ASTM F75 alloys, Laser powder bed fusion, Microstructural characterization, Mechanical propertiesAbstract
This study provides a systematic and bibliometric review of
ASTM F75 cobalt–chromium alloys, focusing on
microstructure and the shift from conventional to laserbased manufacturing. Using combined analytical methods, it
evaluates microstructure, mechanical properties, corrosion
behavior, and biocompatibility. Results show that laserbased techniques such as LPBF and DMLS produce finer grain
sizes (1–10 µm vs. 50–200 µm), leading to improved hardness
(20–40%) and tensile strength (15–30%). Despite challenges
like residual stress and process optimization, these methods
show strong potential for high-performance and sustainable
applications.
References
Muñoz, I. A., and Mischler, S. (2011). Effect of the environment on wear ranking and
corrosion of biomedical CoCrMo alloys. Journal of Materials Science: Materials in
Medicine, 22(3), 437-450.
Hedberg, Y., and Wallinder, O. I. (2014). Metal release and speciation of released
chromium from a biomedical CoCrMo alloy into simulated physiologically relevant
solutions. Journal of Biomedical Materials Research Part B: Applied Biomaterials, 102(4),
-699.
Mantrala, K. M., Das, M., Balla, V. K., Rao, C. S., and Rao, V. K. (2014). Laser-deposited
CoCrMo alloy: Microstructure, wear, and electrochemical properties. Journal of Materials
Research, 29(17), 2021-2027.
Guoqing, Z., Yongqiang, Y., Hui, L., Changhui, S., and Zimian, Z. (2017). Study on the
quality and performance of CoCrMo alloy parts manufactured by selective laser melting.
Journal of Materials Engineering and Performance, 26(6), 2869-2877.
Bawane, K. K., Srinivasan, D., and Banerjee, D. (2018). Microstructural evolution and
mechanical properties of direct metal laser-sintered (DMLS) CoCrMo after heat
treatment. Metallurgical and Materials Transactions A, 49(9), 3793-3811.
Song, C., Zhang, M., Yang, Y., Wang, D., and Jia-Kuo, Y. (2018). Morphology and properties
of CoCrMo parts fabricated by selective laser melting. Materials Science and Engineering:
A, 713, 206-213.
Guoqing, Z., Junxin, L., Jin, L., Chengguang, Z., and Zefeng, X. (2018). Simulation analysis
and performance study of CoCrMo porous structure manufactured by selective laser
melting. Journal of Materials Engineering and Performance, 27(5), 2271-2280.
Bandyopadhyay, A., Shivaram, A., Isik, M., Avila, J. D., Dernell, W. S., and Bose, S. (2019).
Additively manufactured calcium phosphate reinforced CoCrMo alloy: Bio-tribological
and biocompatibility evaluation for load-bearing implants. Additive manufacturing, 28,
-324.
Li, J., Ren, H., Liu, C., and Shang, S. (2019). The effect of specific energy density on
microstructure and corrosion resistance of CoCrMo alloy fabricated by laser metal
deposition. Materials, 12(8), 1321.
Tonelli, L., Fortunato, A., and Ceschini, L. (2020). CoCr alloy processed by selective laser
melting (SLM): Effect of laser energy density on microstructure, surface morphology, and
hardness. Journal of Manufacturing Processes, 52, 106-119.
Santos, C. D., Habibe, A. F., Simba, B. G., Lins, J. F. C., Freitas, B. X. D., and Nunes, C. A.
(2020). CoCrMo-base alloys for dental applications obtained by selective laser melting
(SLM) and CAD/CAM milling. Materials Research, 23(2), e20190599.
Zhao, F., Guo, T., Li, Q., Yin, Y., Zhang, R., and Nan, X. (2022). Effect of solution aging
treatment on microstructure and properties of Fe-0.5 C-11Cr corrosion resistant alloy by
laser cladding. Journal of Alloys and Compounds, 922, 166142.
Li, H., Wang, M., Lou, D., Xia, W., and Fang, X. (2020). Microstructural features of
biomedical cobalt–chromium–molybdenum (CoCrMo) alloy from powder bed fusion to
aging heat treatment. Journal of Materials Science & Technology, 45, 146-156.
Miyake, M., Matsuda, T., Sano, T., Hirose, A., Shiomi, Y., and Sasaki, M. (2020).
Microstructure and mechanical properties of additively manufactured CoCrW alloy using
laser metal deposition. Welding in the World, 64(8), 1397-1407.
Viderščak, D., Schauperl, Z., Šolić, S., Ćatić, A., Godec, M., Kocijan, A., Paulin, I., and Donik,
Č. (2021). Additively manufactured commercial Co-Cr dental alloys: Comparison of
microstructure and mechanical properties. Materials, 14(23), 7350.
Kosec, T., Leban, M. B., Kurnik, M., and Kopač, I. (2021). Comparison of the corrosion
properties of cocrmo dental alloys in artificial saliva. Materials and Technology, 55(6),
-824.
Wai Cho, H. H., Takaichi, A., Kajima, Y., Htat, H. L., Kittikundecha, N., Hanawa, T., and
Wakabayashi, N. (2021). Effect of post-heat treatment cooling conditions on
microstructures and fatigue properties of cobalt chromium molybdenum alloy fabricated
through selective laser melting. Metals, 11(7), 1005.
Hu, Y., Dong, C., Kong, D., Ding, J., He, X., Ni, X., Zhang, L., and Li, X. (2021). Effects of postproduction heat treatment on the mechanical and corrosion behaviour of CoCrMoW alloy manufactured through selective laser melting. Materials Today Communications,
, 102994.
Saini, J. S., Dowling, L., Trimble, D., and Singh, D. (2021). Mechanical properties of
selective laser melted CoCr alloys: A review. Journal of Materials Engineering and
Performance, 30(12), 8700-8714.
Sahasrabudhe, H., Traxel, K. D., and Bandyopadhyay, A. (2021). Understanding wear
behavior of 3D-printed calcium phosphate-reinforced CoCrMo in biologically relevant
media. Journal of the mechanical behavior of biomedical materials, 120, 104564.
Mace, A., Khullar, P., Bouknight, C., and Gilbert, J. L. (2022). Corrosion properties of low
carbon CoCrMo and additively manufactured CoCr alloys for dental applications. Dental
Materials, 38(7), 1184-1193.
Dong, X., Li, N., Yu, J., Qu, Y., Wu, M., Zhou, Y., Shi, H., Peng, H., Zhang, Y., and Yan, J.
(2022). Effect of grain boundary character on isothermal phase transformation and
mechanical properties of Co-Cr-Mo alloy fabricated by selective laser melting. Journal of
Alloys and Compounds, 903, 163904.
Reimann, L., Brytan, Z., and Jania, G. (2022). Influence of filler metal on electrochemical
characteristics of a laser-welded Co-Cr-MoW alloy used in prosthodontics. Materials,
(16), 5721.
Hu, Y., Yao, J., Ao, M., and Dong, C. (2022). Nanoscale precipitate in PBF-LB-manufactured
CoCrMoW alloy and its effect on passive behaviour. Materials Letters, 319, 132295.
Liu, Y., Mace, A., Lee, H., Camargo, M., and Gilbert, J. L. (2022). Single asperity sub-nano
to nanoscale wear and tribocorrosion of wrought CoCrMo and additively manufactured
CoCrMoW alloys. Tribology International, 174, 107770.
Saini, J. S., Dowling, L., Trimble, D., and Singh, D. (2021). Mechanical properties of
selective laser melted CoCr alloys: A review. Journal of Materials Engineering and
Performance, 30(12), 8700-8714.
Qin, P., Chen, L. Y., Liu, Y. J., Zhao, C. H., Lu, Y. J., Sun, H., and Zhang, L. C. (2023). Corrosion
behavior and mechanism of laser powder bed fusion produced CoCrW in an acidic NaCl
solution. Corrosion Science, 213, 110999.
Jiang, W., An, X., Xiao, C., Ni, S., and Song, M. (2023). Effects of heat treatment on the
microstructure and properties of a face-centered cubic CoCrMoW alloy prepared via laser
powder bed fusion. Journal of Alloys and Compounds, 963, 171212.
Shang, R., Yang, B., and Li, Y. (2023). Enhanced anti-corrosion performance of co-cr-mo
alloy in molten Al by prior oxidation treatment. Materials, 16(23), 7449.
Zhang, Y., Lin, W., Zhai, Z., Wu, Y., Yang, R., and Zhang, Z. (2023). Enhancing the
mechanical property of laser powder bed fusion CoCrMo alloy by tailoring the
microstructure and phase constituent. Materials Science and Engineering: A, 862,
Atapour, M., Sanaei, S., Wei, Z., Sheikholeslam, M., Henderson, J. D., Eduok, U., Hosein,
Y. K., Holdsworth, D.W., Hedberg, Y. S., and Ghorbani, H. R. (2023). In vitro corrosion and
biocompatibility behavior of CoCrMo alloy manufactured by laser powder bed fusion
parallel and perpendicular to the build direction. Electrochimica Acta, 445, 142059.
Al-Aloosi, R. A., Comakli, O., Yazici, M., and Taha, Z. A. (2023). Influence of scanning
velocity on a CoCrMoW alloy built via selective laser melting: Microstructure, mechanical,
and tribological properties. Journal of Materials Engineering and Performance, 32(15),
-6724.
Preda, L., Leau, S. A., Donath, C., Neacsu, E. I., Maxim, M. E., Sătulu, V., Paraschiv, A., and
Marcu, M. (2023). Investigation of long-term corrosion of CoCrMoW alloys under
simulated physiological conditions. Metals, 13(11), 1881.
Mace, A., and Gilbert, J. L. (2023). Low cycle fretting and fretting corrosion properties of
low carbon CoCrMo and additively manufactured CoCrMoW alloys for dental and
orthopedic applications. Journal of Biomedical Materials Research Part B: Applied
Biomaterials, 111(9), 1600-1613.
Mohamed, L. Z., Elsayed, A. H., Elkady, O. A., and Abolkassem, S. A. (2023). Physicomechanical, microstructure, and chemical properties of Si/Ti/Nb additions to CoCrMoW
medium entropy alloys. Journal of Materials Research and Technology, 24, 9897-9914.
Man, K., Mazumder, S., Dahotre, N. B., and Yang, Y. (2023). Surface nanostructures
enhanced biocompatibility and osteoinductivity of laser-additively manufactured
CoCrMo alloys. ACS Omega, 8(50), 47658-47666.
Klimek, L., Bułhak, B., and Śmielak, B. (2024). A comparison of the structure and selected
mechanical properties of Cr/Co alloys obtained by casting and selective laser melting.
Journal of Functional Biomaterials, 15(3), 61.
Mani, G., Porter, D., Collins, S., Schatz, T., Ornberg, A., and Shulfer, R. (2024). A review
on manufacturing processes of cobalt-chromium alloy implants and its impact on
corrosion resistance and biocompatibility. Journal of Biomedical Materials Research Part
B: Applied Biomaterials, 112(6), e35431.
Pellegrini, A., Lavecchia, F., Guerra, M. G., and Galantucci, L. M. (2024). Analysis of
microstructure and mechanical properties of CoCrMo alloys processed by metal binder
jetting multi-step technique. Journal of Manufacturing and Materials Processing, 8(6),
Chen, J., Ding, X., Wang, J., Xie, Z., and Wang, S. (2024). Corrosion behavior, metal ions
release and wear resistance of TiN coating deposited on SLM CoCrMo alloy by magnetron
sputtering. Journal of Alloys and Compounds, 1002, 175319.
Alaloosi, R. A., Çomakli, O., Yazici, M., and Taha, Z. A. (2024). Effect of scan speed on
corrosion and tribocorrosion properties of cobalt-chromium alloy in situ produced by
selective laser melting. Rapid Prototyping Journal, 30(3), 405-414.
Sing, S. L., Huang, S., and Yeong, W. Y. (2020). Effect of solution heat treatment on
microstructure and mechanical properties of laser powder bed fusion produced cobalt28chromium-6molybdenum. Materials Science and Engineering: A, 769, 138511.
Vidyasagar, K. C., and Kalyanasundaram, D. (2024). Enhanced corrosion resistance of
CoCrMo by laser-based surface modification. Surface Engineering, 40(1), 100-111.
Varol, T., Aksa, H. C., Yıldız, F., Akçay, S. B., Kaya, G., and Beder, M. (2024). Influence of
post processing on the mechanical properties and wear behavior of selective laser melted
Co-Cr-Mo-W alloys. Tribology International, 192, 109336.
Al-Aloosi, R. A., Taha, Z. A. T., and Çomakli, O. Ç. O. (2024). Influence of scanning velocity
on Co24. 7Cr5Mo5. 4W alloy built via selective laser melting on roughness properties.
Iraqi Journal of Laser, 23(1), 24-37.
Li, H., Song, B., Wang, Y., Zhang, J., Zhao, W., and Fang, X. (2024). Laser powder bed
fusion process optimization of CoCrMo alloy assisted by machine-learning. Journal of
Materials Research and Technology, 33, 3901-3910.
De La Cruz, L. G., Alvaredo, P., Torralba, J. M., and Campos, M. (2024). Material extrusion:
A promising tool for processing CoCrMo alloy with excellent wear resistance for
biomedical applications. Materials & Design, 244, 113089.
Ma, L. Y., Sun, F. Y., Li, Y., and Yu, H. (2024). Mechanical property, corrosion behavior
and cytocompatibility of CoCrMo for dental application: A comparative study of cast and
laser powder bed fusion. Journal of the Mechanical Behavior of Biomedical Materials,
, 106788.
Al Jabbari, Y. S., Dimitriadis, K., Sufyan, A., and Zinelis, S. (2024). Microstructural and
mechanical characterization of six Co-Cr alloys made by conventional casting and
selective laser melting. The Journal of Prosthetic Dentistry, 132(3), 646-e1.
Jiang, W., Li, R., He, J., Ni, S., Wang, L., Chen, Z., Huang, Y., Li, C., Yi, J., and Song, M.
(2024). Nitrogen-doping assisted local chemical heterogeneity and mechanical properties
in CoCrMoW alloys manufactured via laser powder bed fusion. Advanced Powder
Materials, 3(5), 10027.
Mazumder, S., Boban, J., and Ahmed, A. (2025). A comprehensive review of recent
advancements in 3D-printed Co-Cr-based alloys and their applications. Journal of
Manufacturing and Materials Processing, 9(5), 169.
Aktürk, D., Yildiz, M. T., Yurtkuran, E., and Babacan, N. (2025). Microstructural and fatigue
properties of dental structures produced via selective laser melting: Comparing Co-CrMo, Co-Cr-Mo-W and Co-Cr-W alloys. Rapid Prototyping Journal, 31(6), 1280-1290.
Dai, L., Song, C., Fu, H., Chen, H., Yan, Z., Liu, Z., Li, R., Wang, A., Yang, Y., and Yu, J. K.
(2025). Recrystallization induced by heat treatment regulates the anisotropic behavior of
CoCrMo alloys fabricated by laser powder bed fusion. Materials Futures, 4(2), 025001.
Nothnagel, R. M., Vukonic, L., Bauer, C., Váradi, T., Linhardt, P., Franek, F., Nehrer, S., and
Ripoll, R. M. (2025). Tribocorrosion performance and cytotoxicity of additive
manufactured CoCrMo: A benchmark against wrought CoCrMo. Journal of Bio-and TriboCorrosion, 11(1), 2.
Avanzini, A., Petrogalli, C., and Cornacchia, G. (2025). Tribological behavior of a selective
laser melted CoCrMo alloy under different heat treatment, loading, and sliding
conditions. Tribology Transactions, 68(3), 613-19.