Property Enhancement of Electrodeposited p-Cu₂O Thin Films via Hydrothermal Ethanol Etching for Solar Cell Applications Supporting the Sustainable Development Goals (SDGs)

Authors

  • Nurliyana Mohamad Arifin MILA University Author
  • Fariza Mohamad Universiti Tun Hussein Onn Malaysia (UTHM) Author
  • Ming Wei Ping Firmtec Engineering (M) Sdn Bhd Author
  • Mohd Zamzuri Mohammad Zain Universiti Malaysia Perlis Author
  • Masanobu Izaki National Institute of Technology, Nara College Author

Keywords:

Absorber layer, Copper oxide, Electrodeposition, Hydrothermal ethanol etching, Solar cell, Sustainable development goals, Thin film

Abstract

Electrodeposited p-Cu₂O thin films are promising absorber
layers for sustainable solar cell applications, but their
performance is limited by surface defects, high resistivity,
and poor crystallinity. This study investigates hydrothermal
ethanol etching as a post-deposition treatment to enhance
p-Cu₂O thin films on FTO substrates. The treatment improved
crystallinity, refined pyramidal morphology, increased
visible-light absorption, reduced surface roughness, and
lowered electrical resistivity. These enhancements are
attributed to the removal of disordered surface regions and
resistive secondary phases. The results indicate that
controlled hydrothermal ethanol etching is an effective
strategy for improving electrodeposited p-Cu₂O thin films for
sustainable photovoltaic applications.

References

Ahmad Ramli, S., Mohamad, F., Anizam, A. G. A., Ahmad, M. K., Ahmad, N., Mohd Ismail, A.

Z., Mohamad Arifin, N., Maarof, N. A. S., Nurhaziqah, A. M. S., Saputri, D. G., and

Izaki, M. (2022). Properties enhancement of TiO₂ nanorod thin film using

hydrochloric acid etching treatment method. Journal of Materials Science: Materials

in Electronics, 33(20), 16348-16356.

Ait Hssi, A., Atourki, L., Labchir, N., Abouabassi, K., Ouafi, M., Mouhib, H., Ihlal, A., Elfanaoui,

A., Benmokhtar, S., and Bouabid, K. (2020). Structural and optical properties of

electrodeposited Cu₂O thin films. Materials Today: Proceedings, 22, 89-92.

Al-Janabi, S. M. D., and Jumaa, F. A. (2026). Designing and optimal sizing for off-grid PV

system in Al-Muwailiha village/Iraq by using PVsyst and Homer software: A case

study. Semarak Engineering Journal, 1(1), 1-16.

Aldahhan, M. R., and Akkar, H. A. (2026). Design of an intelligent solar SPWM inverter based

on FPGA. Semarak Engineering Journal, 1(1), 62-79.

Ali, K., Sajid, M., Abu Bakar, S., Younus, A., Ali, H., and Rashid, M. Z. (2024). Synthesis of

copper oxide (CuO) via coprecipitation method: Tailoring structural and optical

properties of CuO nanoparticles for optoelectronic device applications. Hybrid

Advances, 6, 100250.

Arifin, N. M., Mohamad, F., Hussin, R., Ismail, A. Z. M., Ramli, S. A., Ahmad, N., Nor, N. H. M.,

Sahdan, M. Z., Zain, M. Z. M., and Izaki, M. (2021). Development of homogenous n-TiO₂/ZnO bilayer/p-Cu₂O heterostructure thin film. Journal of Sol-Gel Science and

Technology, 100(2), 224-231.

Arifin, N. M., Mohamad, F., Hussin, R., Ismail, A. Z. M., Ramli, S. A., Ahmad, N., Nor, N. H. M.,

Sahdan, M. Z., Zain, M. Z. M., and Izaki, M. (2023). Annealing treatment on

homogenous n-TiO₂/ZnO bilayer thin film deposition as window layer for p-Cu₂Obased heterostructure thin film. Coatings, 13(1), 206.

Arifin, N. M., Mohamad, F., Xin, L. Z., Hussin, R., Ismail, A. Z. M., Ramli, S. A., Ahmad, N., Nor,

N. H. M., Sahdan, M. Z., Zain, M. Z. M., and Izaki, M. (2023b). Dependence of

deposition bath temperature for p-electrodeposited-Cu₂O onto n-TiO₂/ZnO bilayer

thin films. Optik, 288, 171205.

Arulkumar, E., Thanikaikarasan, S., and Tesfie, N. (2023). Influence of deposition parameters

for Cu₂O and CuO thin films by electrodeposition technique: A short review. Journal

of Nanomaterials, 2023(1), 8987633.

Ávila-López, A., Cruz, J. C., Díaz-Real, J. A., García-Uitz, K., Cante-Góngora, D., and RodríguezMay, G. (2025). A review of perovskite-based solar cells over the last decade: The

evolution of the hole transport layer and the use of WO₃ as an electron transport

layer. Coatings, 15(2), 1-18.

Bayat, F., and Sheibani, S. (2022). Enhancement of photocatalytic activity of CuO-Cu₂O

heterostructures through the controlled content of Cu₂O. Materials Research

Bulletin, 145, 111561.

Chen, N., Ju, F., Zhou, F., Chen, S., Wei, K., and He, P. (2021). Growth and characterization of

chemical vapor deposition diamond coating incorporated amorphous carbon with

high Raman bands induced by CuO particles. Diamond and Related Materials, 116,

Farid, S., Farhad, U., Cherns, D., Smith, J. A., Fox, N. A., and Fermín, D. J. (2020). Pulsed laser

deposition of single phase n- and p-type Cu₂O thin films with low resistivity.

Materials and Design, 193, 108848.

Fentahun, D. A., Tyagi, A., Singh, S., Sinha, P., Mishra, A., Danayak, S., Kumar, R., and Kar, K.

K. (2021). Tunable optical and electrical properties of p-type Cu₂O thin films. Journal

of Materials Science: Materials in Electronics, 32(8), 11158-11172.

Hirai, H., Miura, Y., Nakajima, A., and Harada, S. (2025). High channel mobility at SiO₂/GaN

interface with different tilt angle trench sidewalls formed by wet etching treatment.

APL Materials, 13(7), 071123.

Hrbek, T., Kúš, P., Yakovlev, Y., Novakova, J., Lobko, Y., Khalakhan, I., Matolín, V., and

Matolínová, I. (2020). Sputter-etching treatment of proton-exchange membranes:

Completely dry thin-film approach to low-loading catalyst-coated membranes for

water electrolysis. International Journal of Hydrogen Energy, 45(41), 20776-20786.

Kaya, D., Aydınoğlu, H. S., Tüzemen, E. Ş., and Ekicibil, A. (2021). Investigation of optical,

electronic, and magnetic properties of p-type NiO thin film on different substrates.

Thin Solid Films, 732, 138800.

Kim, J., Kim, H., Han, G. H., Hong, S., Park, J., Bang, J., Kim, S. Y., and Ahn, S. H. (2022).

Electrodeposition: An efficient method to fabricate self-supported electrodes for

electrochemical energy conversion systems. Exploration, 2(3), 20210077.

Kumar, N., Parui, S. S., Limbu, S., Mahato, D. K., Tiwari, N., and Chauhan, R. N. (2019).

Structural and optical properties of sol-gel derived CuO and Cu₂O nanoparticles.

Materials Today: Proceedings, 41, 237-241.

Lee, C. Y., Joo, Y. H., Kim, M. P., Um, D. S., and Kim, C. I. (2021). Etching characteristics and

changes in surface properties of IGZO thin films by O₂ addition in CF₄/Ar plasma.

Coatings, 11(8), 1-10.

Ma, X., Janssen, R. A. J., and Gelinck, G. H. (2023). Trap-assisted charge generation and

recombination in state-of-the-art organic photodetectors. Advanced Materials

Technologies, 8(16), 2300234.

Mohamad, N., Arifin, N. M., Mohamad, F., Sheng, L. Y., Ismail, A. Z., Ahmad, N., Hisyamudin,

N., Nor, M., and Izaki, M. (2020). Construction of nanorod-TiO₂/p-Cu₂O

heterostructure thin films for solar cell application. International Journal of

Advanced Trends in Computer Science and Engineering, 9(1), 304-310.

Nandiyanto, A. B. D., Kurniawan, T., Bilad, M. R., and Farobie, O. (2025). Harnessing biomass

for Sustainable Development Goals (SDGs): Definition, bibliometric, application,

opportunities, and challenges. Journal of Engineering Science and Technology, 20(4),

-1068.

Nandiyanto, A. B. D., Putri, A. R., Pratiwi, V. A., Ilhami, V. I. N., Kaniawati, I., Kurniawan, T.,

Farobie, O., and Bilad, M. R. (2024). Fourier transform infrared spectroscopy (FTIR) of

pyrolysis of polypropylene microparticles and its chemical reaction mechanism

completed with computational bibliometric literature review to support sustainable

development goals (SDGs). Journal of Engineering Science and Technology, 19(3),

-1104.

Fiandini, M., Nandiyanto, A. B. D., and Muktiarni, M. (2024). Experimental demonstration

for teaching the concept of steam engine power plant to vocational students to

support the sustainability development goals (SDGS) and its comparison to

Indonesian Merdeka curriculum. Journal of Engineering Science and Technology,

(5), 1878-1905.

Ragadhita, R., Nandiyanto, A.B.D., Farobie, O., Kurniawan, T., and Bilad, M.R. (2026).

Definition and role of sustainable materials in reaching global Sustainable

Development Goals (SDGs) completed with bibliometric analysis. ASEAN Journal for

Science and Engineering in Materials, 5(1), 53-100.

Niu, W., Moehl, T., Adams, P., Zhang, X., Lefèvre, R., Cruz, A. M., Zeng, P., Kunze, K., Yang,

W., and Tilley, S. D. (2022). Crystal orientation-dependent etching and trapping in

thermally oxidised Cu₂O photocathodes for water splitting. Energy and

Environmental Science, 15(5), 2002-2010.

Rajak, C., Pramanik, S., Das, S., Santra, S., and Mandal, R. (2025). Evolution of phase, surface

morphology and wettability of sputtered copper thin films on annealing in air:

Formation of CuO/Cu₂O/Cu nanocomposites. Surfaces and Interfaces, 56, 105613.

Rao, P., Yu, Y., Wang, S., Zhou, Y., Wu, X., Li, K., Miao, Z., and Tian, X. (2024). Understanding

the improvement mechanism of plasma etching treatment on oxygen reduction

reaction catalysts. Exploration, 4(1), 20230034.

Rezaei, M. M., Seyed Dorraji, M. S., Hosseini, S. F., and Rasoulifard, M. H. (2025). S-scheme

heterojunction of MoO₃ nanobelts and MoS₂ nanoflowers for photocatalytic

degradation. Scientific Reports, 15(1), 1-12.

Solangi, Y. A., and Magazzino, C. (2025). Evaluating financial implications of renewable

energy for climate action and sustainable development goals. Renewable and

Sustainable Energy Reviews, 212, 115390.

Song, G., Wang, Y., and Tan, D. Q. (2022). A review of surface roughness impact on dielectric

film properties. IET Nanodielectrics, 5(1), 1-23.

Sun, H., Wang, S., Qi, S., Wang, P., Li, R., Shi, B., Zhang, Q., Huang, Q., Xu, S., Zhao, Y., and

Zhang, X. (2023). Surface defects management by in situ etching with methanol for

efficient inverted inorganic perovskite solar cells. Advanced Functional Materials,

(23), 2213913.

Thejasiri, S. A. A. B., Jayathilaka, K. M. D. C., Kafi, F. S. B., Kumara, L. S. R., Seo, O., Yasuno, S.,

Sakata, O., Siripala, W., and Wijesundera, R. P. (2024). Cu₂O homojunction solar cells:

Efficiency enhancement with a high short circuit current. Coatings, 14(8), 932.

Trinkler, L., Dai, D., Chang, L., Chou, M. M. C., Wu, T. Y., Gabrusenoks, J., Nilova, D., Ruska,

R., Berzina, B., and Nedzinskas, R. (2023). Luminescence properties of epitaxial Cu₂O

thin films electrodeposited on metallic substrates and Cu₂O single crystals. Materials,

(12), 4349.

Trisnoaji, Y., Prasetyo, S. D., Choifin, M., Harsito, C., and Anggit, A. (2025). Enhancing

efficiency in small-scale hydropower: A comprehensive review of Archimedes screw

turbine design innovations. Semarak Engineering Journal, 1(1), 1-15.

Winkler, N., Edinger, S., Kaur, J., Wibowo, R. A., Kautek, W., and Dimopoulos, T. (2018).

Solution-processed all-oxide solar cell based on electrodeposited Cu₂O and ZnMgO

by spray pyrolysis. Journal of Materials Science, 53(17), 12231-12243.

Wisz, G., Sawicka-Chudy, P., Sibiński, M., Płoch, D., Bester, M., Cholewa, M., Woźny, J.,

Yavorskyi, R., Nykyruy, L., and Ruszała, M. (2022). TiO₂/CuO/Cu₂O photovoltaic nanostructures prepared by DC reactive magnetron sputtering. Nanomaterials,

(8), 1328.

Wojcieszak, D., Obstarczyk, A., Mańkowska, E., Mazur, M., Kaczmarek, D., Zakrzewska, K.,

Mazur, P., and Domaradzki, J. (2022). Thermal oxidation impact on the

optoelectronic and hydrogen sensing properties of p-type copper oxide thin films.

Materials Research Bulletin, 147, 111646.

Zhu, C., and Panzer, M. J. (2016). Etching of electrodeposited Cu₂O films using ammonia

solution for photovoltaic applications. Physical Chemistry Chemical Physics, 18(9),

-6728.

Zulkifli, M., Mohamad, F., Ahmad, R. S., Mohamad, A. N., Ahmad, M., Muhd, N.,

Mohammad, Z. M., and Izaki, M. (2024). Effect of hydrothermal reaction time and

etching on nanorod TiO₂ thin film. Journal of Advanced Research, 127(1), 120-135.

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Published

2026-12-01