Integrated Experimental, Statistical, and Finite Element Analysis of Nanoparticle-Reinforced Polymer Composites for Advanced Structural Applications Completed with Bibliometric Analysis
Keywords:
Experimental Tests, Fatigue Strength, Fem, MWCNT Nanoparticles, PVDF/UPR CompositesAbstract
This study investigates the mechanical and tribological behavior of
polyvinylidene fluoride (PVDF)/unsaturated polyester resin (UPR)
composites reinforced with 1–5% multi-walled carbon nanotubes
(MWCNTs). Research on PVDF-based nanocomposites has
increased significantly, according to a quick bibliometric screening
of Scopus-indexed publications. MWCNTs were found to be one of
the most influential reinforcement keywords, indicating a high
level of interest in mechanically optimized polymer systems
worldwide. In this study, specimens were tested for tensile,
flexural, hardness, impact, wear, and reversed-bending fatigue
performance. Results reveal that 3% MWCNT provides optimal
strengthening, improving tensile and flexural properties,
hardness, wear resistance, and fatigue life while reducing void
content. Finite element simulations using ANSYS aligned with
experimental findings, showing deviations below 10%. Statistical
analysis (ANOVA) confirmed significant effects of MWCNT
content. Overall, PVDF/UPR–MWCNT composites demonstrate
excellent potential for advanced lightweight structural
applications.
References
Alaaeddin, M. H., Sapuan, S. M., Zuhri, M. Y. M., Zainudin, E. S., and Al-Oqla, F. M. (2019).
Physical and mechanical properties of polyvinylidene fluoride–short sugar palm fiber
nanocomposites. Journal of Cleaner Production, 235, 473–482.
Al-Ameen, E. S., Abdulla, F. A., and Ogaili, A. A. F. (2020). Effect of nano TiO₂ on fracture
toughness of fiberglass/epoxy in hot climates. IOP Conference Series: Materials Science
and Engineering, 870, 012170.
Al-Ameen, E. S., Al-Sabbagh, M. N. M., Ogaili, A. A. F., and Hassan, A. K. (2022). Role of prestressing on anti-penetration properties of Kevlar/epoxy plates. International Journal of
Nanoelectronics and Materials, 15, 293–302.
Bidsorkhi, H. C., D’Aloia, A. G., De Bellis, G., Proietti, A., Rinaldi, A., Fortunato, M., Ballirano,
P., Bracciale, M. P., Santarelli, M. L., and Sarto, M. S. (2017). Nucleation effect of
unmodified graphene nanoplatelets on PVDF/GNP film composites. Materials Today
Communications, 11, 163–173.
Fu, S., Sun, Z., Huang, P., Li, Y., and Hu, N. (2019). Some basic aspects of polymer
nanocomposites: A critical review. Nano Materials Science, 1, 2–30.
Hamdan, Z. K., Ogaili, A. A. F., Jebur, N. A., Abdulla, F. A., Al-Ameen, E. S., and Meteab, Z. W.
(2024). Waste eggshell and sawdust as reinforcements for sustainable polyester
composites. Jurnal Teknologi (Sciences and Engineering). 87(1), 73-88.
Hosur, M., Mahdi, T. H., Islam, M. E., and Jeelani, S. (2017). Mechanical and viscoelastic
properties of epoxy nanocomposites reinforced with carbon nanotubes, nanoclay, and
binary nanoparticles. Journal of Reinforced Plastics and Composites, 36, 667–684.
Janićijević, A., Filipović, S., Sknepnek, A., Salević-Jelić, A., Jančić-Heinemann, R., Petrović, M.,
Petronijević, I., Stamenović, M., Živković, P., and Potkonjak, N. (2024). Structural,
mechanical, and barrier properties of polyvinylidene fluoride–bacterial nanocellulose
hybrid composite. Polymers, 16, 1033.
Jweri, A.-R. K., Al-Haddad, L. A., Ogaili, A. A. F., Jaber, A. A., and Al-Karkhi, M. I. (2025). Edgeintelligent leak detection using CatBoost. Clean Energy Science and Technology, 3, 398.
Koç, M., Dönmez, Ç. E. D., Paralı, L., Sarı, A., and Aktürk, S. (2022). Piezoelectric and
magnetoelectric evaluations on PVDF/CoFe₂O₄ nanogenerators for energy harvesting
applications. Journal of Materials Science: Materials in Electronics, 33, 8048–8064.
Kong, X., Wang, Q.-Z., Wang, Y.-F., Huo, H.-M., Kou, F.-Q., Zhang, S.-B., Zhao, J., Zhang, D.,
Hao, L., and Chang, Y.-J. (2025). Synergistic manipulation of PVDF membrane structure
via in-situ esterification for anti-fouling membranes. Journal of Membrane Science, 715,
Ma, P.-C., Siddiqui, N. A., Marom, G., and Kim, J.-K. (2010). Dispersion and functionalization
of carbon nanotubes for polymer nanocomposites. Composites Part A: Applied Science
and Manufacturing, 41, 1345–1367.
Mahdi, N. M., Jassim, A. H., Abulqasim, S. A., Basem, A., Ogaili, A. A. F., and Al-Haddad, L. A.
(2024). Leak detection using ANN in water distribution systems. Desalination and Water
Treatment, 320, 100685.
Mathew, S., Jan, H., and Prasad, V. (2023). Conduction mechanism in PVDF/graphene oxide
composites. Physica B: Condensed Matter, 666, 415116.
Mejbel, B. G., Sarow, S. A., Al-Sharify, M. T., Al-Haddad, L. A., and Ogaili, A. A. F. (2024). Data
fusion and random forest for machinery failure diagnosis. Journal of Failure Analysis and
Prevention, 24(6), 2979-2989.
Metteb, Z. W., Ogaili, A. A. F., Mohammed, K. A., Alsayah, A. M., Hamzah, M. N., Al-Sharify, Z.
T., Jaber, A. A., and Njim, E. K. (2025). Optimization of hybrid core designs in 3D-printed
PLA+ sandwich structures. Indonesian Journal of Science and Technology, 10, 207–236.
Mohammed, K. A., Al-Sabbagh, M. N. M., Ogaili, A. A. F., and Al-Ameen, E. S. (2020).
Experimental analysis of hot machining parameters in crankshaft finishing. Journal of
Mechanical Engineering Research and Developments, 43, 105–114.
Mohammed, K. A., Ogaili, A. A. F., Taha, A. W. A., and Alsayah, A. M. (2025). Evaluating spot
welds via mechanical testing and finite element modeling. Applied Engineering Letters,
, 77–89.
Mubarokah, S. L., Anwar, S., Nisa, K., Miftah, H., Hastuti, A., and Nandiyanto, A. B. D. (2024).
Bibliometrics study on agro-economy of biochar. Journal of Engineering Science and
Technology, 19, 142-152.
Kumar, N. C., Prabhakar, M. N., and Jung-il, S. (2022). PVDF green nanofibers as potential
carriers for improving self-healing and mechanical properties of carbon fiber/epoxy
prepregs. Nanotechnology Reviews, 11, 1890–1900.
Nandiyanto, A. B. D., Ragadhita, R., Al Husaeni, D. N., and Nugraha, W. C. (2023). Research
trend on the use of mercury in gold mining: Literature review and bibliometric analysis.
Moroccan Journal of Chemistry, 11(1), 1-19.
Nandiyanto, A. B. D., Syazwany, A. N., Syarafah, K. N., Syuhada, T. S., Ragadhita, R., Piantari,
E., Farobie, O., and Bilad, M. R. (2024). Utilization of bamboo powder in the production
of non-asbestos brake pads: Computational bibliometric literature review analysis and
experiments to support sustainable development goals (SDGs). Automotive Experiences,
(1), 111-131.
Nassir, L. M., Ramadhan, A. J., Al-Sharify, N. T., Khalaf, M. I., Ogaili, A. A. F., Jaber, A. A., and
Al-Sharify, Z. T. (2025). Robust multi-state EEG cognitive classification with CatBoost.
International Journal of Robotics and Control Systems, 5, 968–989.
Ndeh, N. T., Sairiam, S., and Nuisin, R. (2024). Graphene oxide-chitosan coated PVDF
adsorptive microfiltration membrane: Enhancing dye removal and antifouling properties.
International Journal of Biological Macromolecules, 282, 137005.
N'diaye, A. D., Kankou, M. S. A., Hammouti, B., Nandiyanto, A. B. D., and Al Husaeni, D. F.
(2022). A review of biomaterial as an adsorbent: From the bibliometric literature review,
the definition of dyes and adsorbent, the adsorption phenomena and isotherm models,
factors affecting the adsorption process, to the use of typha species waste as adsorbent.
Communications in Science and Technology, 7(2), 140-153.
Nivedhitha, D. M., and Jeyanthi, S. (2023). Polyvinylidene fluoride: An advanced futuristic
smart polymer material—A comprehensive review. Polymer Advanced Technologies, 34,
–505.
Ogaili, A. A. F., Al-Ameen, E. S., Kadhim, M. S., and Mustafa, M. N. (2020). Evaluation of
mechanical and electrical properties of GFRP composite strengthened with hybrid
nanomaterial fillers. AIMS Materials Science, 7, 93–102.
Ogaili, A. A. F., Basem, A., Kadhim, M. S., Al-Sharify, Z. T., Jaber, A. A., Njim, E. K., Al-Haddad,
L. A., Hamzah, M. N., and Al-Ameen, E. S. (2024). Effect of chopped carbon fibers on 3Dprinted PLA parts. Journal of Composites Science, 8, 273.
Ragadhita, R., and Nandiyanto, A. B. D. (2024). A bibliometric analysis of materials
engineering education: Trends and their implications for research and education. ASEAN
Journal of Educational Research and Technology, 3(3), 327-344.
Saha, A., Chakraborty, T., Saha, S., Dutta, S., Kundu, T., Mukherjee, S., Das, S., and Sutradhar,
S. (2025). Superior EMI shielding behaviour of multi-layer PVDF laminated
nanocomposites with W-type hexaferrite fillers. Materials Research Bulletin, 183,
Saha, S., Yauvana, V., Chakraborty, S., and Sanyal, D. (2019). Synthesis and characterization
of PVDF nanofiber for piezoelectric sensors. Materials Today: Proceedings, 18, 1450–
Sarow, S. A., Flayyih, H. A., Bazerkan, M., Al-Haddad, L. A., Al-Sharify, Z. T., and Ogaili, A. A. F.
(2024). XGBoost prediction of water yield in solar stills. Discover Sustainability, 5, 510.
Saxena, P., and Shukla, P. (2021). A comprehensive review on properties and applications of
poly(vinylidene fluoride). Advanced Composites and Hybrid Materials, 4, 8–26.
Sriyanti, I., Dani, R., Almafie, M. R., Partan, R. U., Idjan, M. K. N. A., and Marlina, L. (2024a).
Optimization of diameter and mechanical properties of polyacrylonitrile/polyvinylidene
fluoride/graphene oxide coconut shell composite nanofiber mats using response surface
methodology. Case Studies in Chemical and Environmental Engineering, 10, 101030.
Sriyanti, I., Ramadhani, R. F., Almafie, M. R., Idjan, M. K. N. A., Syafri, E., Solihah, I., Sanjaya,
M. R., Jauhari, J., and Fudholi, A. (2024b). Physicochemical and mechanical properties of polyvinylidene fluoride nanofiber membranes. Case Studies in Chemical and
Environmental Engineering, 9, 100588.
Vicente, J., Costa, P., Lanceros-Mendez, S., Abete, J. M., and Iturrospe, A. (2019).
Electromechanical properties of PVDF-based polymers reinforced with
nanocarbonaceous fillers for pressure sensing applications. Materials, 12, 3545.
Winey, K. I., and Vaia, R. A. (2007). Polymer nanocomposites. MRS Bulletin, 32, 314–322.
Yangzhou, Z., Weifeng, Y., Chaoyang, Z., Bin, G., and Ning, H. (2018). Piezoelectricity of nanoSiO₂/PVDF composite film. Materials Research Express, 5, 105506.
Yi, G., Li, J., Henderson, L. C., Lei, W., Du, L., and Zhao, S. (2022). Enhancing thermal
conductivity of polyvinylidene fluoride composites by carbon fiber: Length effect of the
filler. Polymers, 14, 4599.
Zheng, J., Zhou, X., Wang, B., Dai, F., and Liu, J. (2024). Modified PVDF/PMMA/SiO₂ composite
nanofibrous membrane in airborne filtration: Transparency, mechanical properties and
filtration performance. Journal of Environmental Chemical Engineering, 12, 114109.
