Upcycling Polymeric Waste into Interpenetrating Polymer Network Adsorbents for Sustainable Wastewater Treatment

Authors

  • Ghayda Yaseen Al Kindi University of Technology-Iraq Author
  • Rana J. Kadhim University of Technology-Iraq Author
  • Elaf Abd Al-Azal Ihsan University of Technology-Iraq Author
  • Sinan A. Al-Haddad University of Technology-Iraq Author

Keywords:

Adsorption, Batch reactor, Epoxy resin, Pharmaceutical waste, Polystyrene

Abstract

This study reports the sustainable synthesis,
characterization, and application of Interpenetrating
Polymer Networks (IPNs) derived from post-consumer
polystyrene kitchenware and epoxy resin residues as a costeffective adsorbent for amoxicillin removal from
wastewater. The conversion of these polymeric wastes into
functional materials aligns with circular economy strategies.
Batch adsorption experiments were carried out to examine
the effects of key operational parameters, including
adsorbent dosage, contact time, and solution pH. The results
showed a maximum removal efficiency (96%) at an
adsorbent dosage of 0.1 g and pH 5. Kinetic analysis indicated
that the adsorption process followed a pseudo-second-order
model, suggesting chemisorption as the dominant
mechanism, with an equilibrium adsorption capacity (qe) of
8.13 mg/g. Isotherm modeling demonstrated that the
Langmuir model provided the best fit, confirming monolayer
adsorption on a homogeneous surface, while Temkin
parameters indicated favorable adsorption energetics.
Overall, these findings highlight the potential of wastederived IPNs as eco-friendly and highly effective materials for
removing pharmaceutical contaminants from aqueous
environments, contributing to the advancement of
sustainable wastewater treatment technologies.

 

References

Adeel, M., Grasel Frois, C. F., Berruti, I., Sirtori, C., Malato, S., and Rizzo, L. (2025). Activation

of peroxymonosulfate by(sunlight)FeCl3-modified biochar for efficient degradation of

contaminants of emerging concern: Comparison with H2O2 and effect of

microplastics. Chemical Engineering Journal, 507, 160782.

Al Kindi, G. Y., and Al-Haidri, H. A. (2023). Removal of pharmaceutical residues in 2D and 3D

electrochemical processes by using orange peels. Innovative Infrastructure Solutions,

(6), 171.

Alenzi, A., Hunter, C., Spencer, J., Roberts, J., Craft, J., Pahl, O., and Escudero, A. (2021).

Pharmaceuticals' effect and removal, at environmentally relevant concentrations,

from sewage sludge during anaerobic digestion. Bioresource Technology, 319, 124102.

Al-Kindi, G. Y., and Al-Haidri, H. A. (2021). The removal of ibuprofen drugs residues from

municipal wastewater by Moringa Oleifera Seeds. Journal of Ecological Engineering,

(1), 83–94.

Al-Kindi, G. Y., and Alnasrawy, S. T. (2022). Tetracycline remove from synthetic wastewater

by using several methods. Journal of Ecological Engineering, 23(5), 137-148.

Al-Kindi, G. Y., Ani, F. H. A. L., Al-Bidri, N. K., and Alhaidri, H. A. (2021). Diclofenac removal

from wastewater by activated carbon. IOP Conference Series: Earth and Environmental

Science, 779(1), 012091.

Chai, W. S., Cheun, J. Y., Kumar, P. S., Mubashir, M., Majeed, Z., Banat, F., Ho, S.-H., and Show,

P. L. (2021). A review on conventional and novel materials towards heavy metal

adsorption in wastewater treatment application. Journal of Cleaner Production, 296,

Chen, Z., Zhang, L., Song, Y., He, J., Wu, L., Zhao, C., Xiao, Y., Li, W., Cai, B., Cheng, H., and Li,

W. (2015). Hierarchical targeted hepatocyte mitochondrial multifunctional chitosan

nanoparticles for anticancer drug delivery. Biomaterials, 52, 240–250.

Codina, A. S., Lumbaque, E. C., and Radjenovic, J. (2025). Electrochemical removal of

contaminants of emerging concern with manganese oxide-functionalized graphene

sponge electrode. Chemical Engineering Journal, 508, 160940.

Dragan, E. S. (2014). Design and applications of interpenetrating polymer network hydrogels.

A review. Chemical Engineering Journal, 243, 572–590.

Fraiha, O., Zaki, N., Hadoudi, N., Salhi, A., ElYoussfi, A., Amhamdi, H., and Ahari, M. (2024).

Adsorption-based removal of amoxicillin from aqueous environments: A mini review.

E3S Web of Conferences, 527, 03012.

Gao, J., Wu, J., Chen, S. and Chen, Y. (2024). Nitrogen removal from pharmaceutical

wastewater using simultaneous nitrification–denitrification coupled with sulfur

denitrification in full-scale system. Bioresource Technology, 393, 130066.

Harris, J. D., Wade, E. A., Ellison, E. G., Pena, C. C., Bryant, S. C., McKibben, N. L., and Chase, J.

R. (2022). Zinc–Acetate–Amine Complexes as Precursors to ZnO and the Effect of the

Amine on Nanoparticle Morphology, Size, and Photocatalytic

Activity. Catalysts, 12(10), 1099.

Hayouni, W., Pistre, S., Chkir, N., and Zouari, K. (2025). Contaminants of emerging concern

(CECs) as indicators of pollution and hydrological processes in an anthropized Mediterranean water basin: Case of the Kasserine Basin (Central Tunisia). Science of

The Total Environment, 984, 179744.

Hu, J., Liu, Y., Zhang, X., Chen, Z., Tang, M., Lyu, Y., You, X., Helbling, D. E., and Sun, W. (2025).

Integrated wide-scope and class-specific nontarget analysis reveals a broad spectrum

of organic micropollutants in an urban river. Water Research, 285, 124145.

Ibrahim, T. N. B. T., Feisal, N. A. S., Kamaludin, N. H., Cheah, W. Y., How, V., Bhatnagar, A., Ma,

Z., and Show, P. L. (2023). Biological active metabolites from microalgae for healthcare

and pharmaceutical industries: A comprehensive review. Bioresource Technology,

, 128661.

Jin, S.-R., Lee, K.-Y., Park, S.-H., Cheon, J.-M., Kang, S. Bin, and Cho, C.-W. (2025). Aminefunctionalized cellulose for the efficient removal of anionic micropollutants from

aqueous environments: Development, characterization, and modeling. Journal of

Water Process Engineering, 75, 107940.

Kargule, B. B., Al-Asadi, M., Al-Anssari, S., Aljibori, H. S. S., Hamzah, H. T., Tastambek, K. T.,

Abdullah, T. A., and Abdullah, O. I. (2025). Sustainable removal of dyes from

wastewater using eggshell-derived calcium carbonate nanoparticles: Adsorption

isotherms, kinetics, and thermodynamic analysis supporting sustainable development

goals (SDGs). ASEAN Journal of Science and Engineering, 5(2), 369–394.

Kindi, G. Y. Al, Kadhim, R. J., Azeez, H. S., Abdulrahman, S. M., and Al-Haddad, S. A. (2025).

Adsorptive removal of Zinc and Lead Ions from industrial wastewater using Al-Fe

Pillared Silty Clay: Kinetic and Isothermal Analysis. Surfaces and Interfaces, 69, 106824.

Laksaci, H., Belhamdi, B., Khelifi, O., Khelifi, A., and Trari, M. (2023). Elimination of amoxicillin

by adsorption on coffee waste based activated carbon. Journal of Molecular Structure,

, 134500.

Lee, K.-Y., Cho, B.-G., Jin, S.-R., Park, S.-H., Cheon, J.-M., and Cho, C.-W. (2025). Experimental

characterization and QSAR modeling of maximum uptake and distribution factor for

neutral and ionic micropollutants on granular activated carbon in artificial and real

wastewaters. Separation and Purification Technology, 373, 133549.

Lin, X., Chan, K., Kingkhambang, K., Hayashi, H., and Zinchenko, A. (2024). Hydrothermal

preparation of pharmaceuticals adsorbents from chitin and chitosan: Optimization

and mechanism. Bioresource Technology, 414, 131583.

Liu, T., Li, Y., Du, Q., Sun, J., Jiao, Y., Yang, G., Wang, Z., Xia, Y., Zhang, W., Wang, K., Zhu, H.,

and Wu, D. (2012). Adsorption of methylene blue from aqueous solution by graphene.

Colloids and Surfaces B: Biointerfaces, 90, 197–203.

Mohammed, M. N., Abdullah, O. I., Jweeg, M. J., Aljibori, H. S. S., Abdullah, T. A., Alawi, N. M.,

Rasheed, R. T., Meharban, F., Hamzah, H. T., and Al-Obaidi, Q. (2025). Comprehensive

review on wastewater treatment using nanoparticles: Synthesis of iron oxide magnetic

nanoparticles, publication trends via bibliometric analysis, applications, enhanced support strategies, and future perspectives. ASEAN Journal of Science and

Engineering, 5(1), 1–30.

Mondal, S., Asif, M. B., Nguyen, T. S., Ismoili, A., and Yavuz, C. T. (2025). Fluorinated porous

organic polymers for efficient adsorption of charged organic micropollutants from

water. Polymer, 333, 128651.

Munyengabe, A., Banda, M. F., and Augustyn, W. (2025). Predicting plant uptake of potential

contaminants of emerging concerns using machine learning models (2018–2025): A

global review. Results in Engineering, 27, 106050.

Radu, C.-D., Sandu, I., Diaconescu, R., Bercu, E., and Aldea, H.-A. (2014). Statistic modelling

and optimization of the dyeing process of melana fibres with victoria blue b dye in the

presence of anionic retarders. Revista De Chimie, 65(7), 797–802.

Sheng, D. P. W., Bilad, M. R., and Shamsuddin, N. (2023). Assessment and optimization of

coagulation process in water treatment plant: A review. ASEAN Journal of Science and

Engineering, 3(1), 79–100.

Singh, P. K., Bhattacharjya, R., Saxena, A., Thakur, I. S., and Tiwari, A. (2022). Envisaging the

role of pharmaceutical contaminant 17-β estradiol on growth and lipid productivity of

marine diatom Chaetoceros gracilis. Bioresource Technology, 346, 126642.

Wang, Q., Nie, S., Zietzschmann, F., Rietveld, L. C., Liu, F., Yang, M., and Yu, J. (2025). Mitigating NOM

competition against micropollutant adsorption through staged dosing of activated carbon:

Loading redistribution of NOM competitors? Separation and Purification Technology, 377,

Yang, C., Yang, J., Lv, Y., Shi, Y., Cui, D., Yin, M., Li, L., Zhang, J., and Xu, C. (2025). Suspect and

non-target screening for emerging contaminants of potential concern and risk

assessment in wastewater treatment plants: A case study of a typical industrial city in

China. Science of The Total Environment, 989, 179857.

Downloads

Published

2026-03-01