Photocatalytic Removal of Toxic Metals from Tannery Wastewater using Green Synthesized Zinc Oxide Nanoparticles

Authors

  • Tyosue Christopher Kpega Ahmadu Bello University, Nigeria Author
  • James Dama Habila Habila Ahmadu Bello University, Nigeria Author
  • Idongesit Edem Okon Okon Ahmadu Bello University, Nigerian Institute of Transport Technology Author
  • Patricia Adama Ekwumemgbo Ahmadu Bello University, Nigeria Author

Keywords:

Heavy metals, Photocatalysis, Physiochemical parameters, Tannery Wastewater, Zinc oxide nanoparticles

Abstract

Water is an important natural resource and is vital to all living
organisms. However, increased industrialization and
urbanization have led to water pollution. This research
aimed at removing some toxic metals from tannery
wastewater using already green synthesized zinc oxide
nanoparticles (ZnO-NPs). The treatment method used was
photocatalytic degradation. The concentrations of Cr, Cu,
and Pb in the wastewater were found to be above the
standard recommended by WHO and the National
Environmental Standards Regulatory and Enforcement
Agency (NESREA) while those of Ni, Mn, and Co were within
the acceptable limit. The photocatalytic degradation using
the ZnO-NPs was effective in the treatment of the metals: Cr,
Co, Cu, Mn, Ni, and Pb as their concentration in the treated
tannery wastewater were significantly lower than that in the
untreated wastewater except for Mn. Based on the results,
photocatalytic degradation using green synthesized ZnO-NPs
has proven to be a viable method for the degradation of
tannery wastewater.

Author Biography

  • Tyosue Christopher Kpega, Ahmadu Bello University, Nigeria

    Ahmadu Bello University, Nigeria

References

Abbasi, M., Rafique, U., Murtaza, G., and Ashraf, M. A. (2018). Synthesis, characterisation and

photocatalytic performance of ZnS coupled Ag2S nanoparticles: A remediation model for

environmental pollutants. Arabian journal of chemistry, 11(6), 827-837.

Aga, B., and Brhane, G. (2014). Determination the level of some heavy metals (Mn and Cu) in

drinking water using wet digestion method of Adigrat Town. Technology Enhancement

and Emerging Engineering Research, 2(10), 32-36.

Bahiru, D. B. (2020). Determination of heavy metals in wastewater and their toxicological

implications around eastern industrial zone, Central Ethiopia. Journal of Environmental

Chemistry and Ecotoxicology, 12(2), 72-79.

Bernard, E., and Ogunleye, A. (2015). Evaluation of tannery effluent content in Kano

metropolis, Kano State Nigeria. International Journal of Physical Sciences, 10(9), 306-310.

Bhatnagar, M.K., Singh, R., Gupta, S., and Bhatnagar, P. (2013). Study of tannery wastewaters

and its effects on sediments of river Ganga in special reference to heavy metals at Jajmau,

Kanpur, India. Journal of Environmental Research and Development, 8(1),56-59.

Boruah, P. K., Yadav, A., and Das, M. R. (2020). Magnetic mixed metal oxide nanomaterials

derived from industrial waste and its photocatalytic applications in environmental

remediation. Journal of Environmental Chemical Engineering, 8(5), 104297.

Briffa, J., Sinagra, E., and Blundell, R. (2020). Heavy metal pollution in the environment and

their toxicological effects on humans. Heliyon, 6(9), e04691.

Cheraghi, M., Lorestani, B., and Yousefi, N. (2009). Effect of waste water on heavy metal

accumulation in Hamedan Province vegetables. International Journal of Botany, 5(2),

-193.

Dan’Azumi, S., and Bichi, M. H. (2010). Industrial pollution and heavy metals profile of

Challawa River in Kano, Nigeria. Journal of Applied Sciences in Environmental

Sanitation, 5(1), 23-29.

Deepali, K. K., and Gangwar, K. (2010). Metals concentration in textile and tannery effluents,

associated soils and ground water. New York Science Journal, 3(4), 82-89.

Ferreira, C. R., and Gahl, W. A. (2017). Disorders of metal metabolism. Translational science

of rare diseases, 2(3-4), 101-139.

Fouda, A., Hassan, S. E. D., Saied, E., and Azab, M. S. (2021). An eco-friendly approach to

textile and tannery wastewater treatment using maghemite nanoparticles (γ-Fe2O3-NPs)

fabricated by Penicillium expansum strain (Kw). Journal of Environmental Chemical

Engineering, 9(1), 104693.

Gong, F., Chen, J., Han, X., Zhao, J., Wang, M., Feng, L., and Cheng, L. (2018). Core–shell

TaOx@ MnO 2 nanoparticles as a nano-radiosensitizer for effective cancer

radiotherapy. Journal of Materials Chemistry B, 6(15), 2250-2257.

Kalsoom, A., and Batool, R. (2020). Biological and nonbiological approaches for treatment of

Cr (VI) in Tannery Effluent. Emerging Eco-friendly Green Technologies for Wastewater

Treatment, 18, 147-170.

Khan, S. A., Noreen, F., Kanwal, S., Iqbal, A., and Hussain, G. (2018). Green synthesis of ZnO

and Cu-doped ZnO nanoparticles from leaf extracts of Abutilon indicum, Clerodendrum

infortunatum, Clerodendrum inerme and investigation of their biological and

photocatalytic activities. Materials Science and Engineering: C, 82, 46-59.

Khan, S. H., and Pathak, B. (2020). Zinc oxide based photocatalytic degradation of persistent

pesticides: A comprehensive review. Environmental Nanotechnology, Monitoring and

Management, 13, 100290.

Khan, Z. I., Ahmad, T., Safdar, H., Nadeem, M., Ahmad, K., Bashir, H., and Dogan, Y. (2020).

Accumulation of cobalt in soils and forages irrigated with city effluent. Egyptian Journal

of Botany, 60(3), 855-863.

Naseem, T., and Durrani, T. (2021). The role of some important metal oxide nanoparticles for

wastewater and antibacterial applications: A review. Environmental Chemistry and

Ecotoxicology, 3, 59-75.

Nur-E-Alam, M., Mia, M. A. S., Ahmad, F., and Rahman, M. M. (2020). An overview of

chromium removal techniques from tannery effluent. Applied Water Science, 10(9), 205-

Okon, I. E., Anweting, I. B., and Danzarami, D. A. (2023). Effect of soil heavy metal

concentrations on early growth performance of Cowpea (Vigna unguiculata) and

groundnut (Arachis hypogea) seeds from Uyo, Nigeria. Journal of Materials and

Environmental Science, 14 (5), 602, 612.

Okon, I. E., Anweting, I. B., and Nwokem, N. C. (2022). A study on heavy metals pollution levels

in water and sediment of River Kubani Dam, Zaria, Nigeria. Pacific Journal of Science and

Technology, 23(2), 107-116.

Oruko, R. O., Selvarajan, R., Ogola, H. J. O., Edokpayi, J. N., and Odiyo, J. O. (2020).

Contemporary and future direction of chromium tanning and management in subSaharan Africa tanneries. Process Safety and Environmental Protection, 133, 369-386.

Raizada, P., Sudhaik, A., and Singh, P. (2019). Photocatalytic water decontamination using

graphene and ZnO coupled photocatalysts: A review. Materials Science for Energy

Technologies, 2(3), 509-525.

Reda, A. H. (2015). Study on the pollution levels of trace metals from modjo tannery effluent

in the surrounding river water and soil. Science Journal of Analytical Chemistry, 3(5), 56-

Salem, S. S., Mohamed, A., El-Gamal, M., Talat, M., and Fouda, A. (2019). Biological

decolorization and degradation of azo dyes from textile wastewater effluent by

Aspergillus niger. Egyptian Journal of Chemistry, 62(10), 1799-1813.

Shaibu, A. N., and Audu, A. A. (2019). Evaluation of physiochemical parameters and some

heavy metals from tannery effluents of Sharada and Challawa Industrial Areas of Kano

State, Nigeria. Nigerian Journal of Basic and Applied Sciences, 27(2), 162-171.

Todorović, Z., Polić, P., Đorđević, D., and Antonijević, S. (2001). Lead distribution in water and

its association with sediment constituents of the" Barje" lake (Leskovac,

Yugoslavia). Journal of the Serbian Chemical Society, 66(10), 697-708.

Ugulu, I. (2015). Determination of heavy metal accumulation in plant samples by

spectrometric techniques in Turkey. Applied Spectroscopy Reviews, 50(2), 113-151.

Ye, W., Liu, H., Lin, F., Lin, J., Zhao, S., Yang, S., and Van der Bruggen, B. (2019). High-flux

nanofiltration membranes tailored by bio-inspired co-deposition of hydrophilic g-C3-N4

nanosheets for enhanced selectivity towards organics and salts. Environmental Science:

Nano, 6(10), 2958-2967.

Yusuff, R. O., and Sonibare, J. A. (2004). Characterization of textile industries’ effluents in

Kaduna, Nigeria and pollution implications. Global Nest: International Journal, 6(3), 212-

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Published

2026-03-01